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class="Crumb"> <b>您當前的位置：</b><a href="/">首頁</a><em>></em> <a href="/Article-index.html" class="Themefont">下載</a><em>></em><a href="/Articles-72959.html" class="Themefont">行業新聞</a> </div> </div>  <div class="row"> <div class="news-nr-box"> <style> body .news-nr-box h1{ font-size:18px; font-family:Airal; text-align:center; line-height:25px; padding: 10px 0; margin:0px; color:#333; } </style> <div class="news1-title"> <h1>酯交換法生產碳酸二甲酯廢氣治理工藝</h1> <h6> <span>2022-04-06</span> <span>　來自:  淄博清新環?？萍加邢薰? </span> <span style="margin-left:10px;">瀏覽次數:820</span> </h6> </div> <p style="text-indent: 2em; text-align: center;">碳酸二甲酯生產工藝產生的<a href="/Article-detail-id-1835559.html" title="廢氣治理方案"><strong>廢氣治理方案</strong></a></p><p style="text-indent: 2em; text-align: left;">碳酸二甲酯生產工藝，國內一般采用環氧丙烷和二氧化碳加催化劑在０．６ｍｐａ，１７０攝氏度下得到粗碳酸丙烯酯，經過負壓精餾提純后得到，精碳酸丙烯酯，此時產生大量<a href="/Article-detail-id-2945299.html" title="廢氣"><strong>廢氣</strong></a>，第二部，碳酸丙烯酯和甲醇在１．０ｍｐａ與甲醇鈉共存，反應生成碳酸二甲酯，碳酸二甲酯和甲醇共沸物，經精餾塔脫出甲醇，回收得到丙二醇，未反應的碳酸丙烯酯和甲醇循環使用，其中在丙二醇減壓精餾過程中產生大量的甲醇廢氣，本工藝系統解決，碳酸丙烯酯生產過程產生的廢氣，及碳酸二甲酯生產過程產生廢氣，最終達標排放。</p><p style="text-indent: 2em; text-align: left;">碳酸二甲酯和碳酸丙烯酯廢氣，甲醇廢氣和碳酸丙烯酯廢氣經絕氧收集，兩條之路分別設有開關閥，可以根據裝置的運行情況，單獨切換，本裝置碳酸二甲酯及甲醇廢氣入<a href="/Article-detail-id-1269834.html" title="冷凝回收裝置"><strong>冷凝回收裝置</strong></a>，采用深度<a href="/Article-detail-id-2942073.html" title="冷凝"><strong>冷凝</strong></a>工藝，根據飽和析出原理，９５％的甲醇可以析出，<a href="/Article-detail-id-1202688.html" title="冷凝回收效率"><strong>冷凝回收效率</strong></a>可以達到９５％以上。經過<a href="/Article-detail-id-1290021.html" title="冷凝回收"><strong>冷凝回收</strong></a>后廢氣進入一套<a href="/Article-detail-id-2949221.html" title="燃燒"><strong>燃燒</strong></a>式ＲＴＯ裝置，經焚燒后氣體排放低于現行排放標準要求。</p><p style="text-indent: 2em; text-align: left;">為保證<a href="/Article-detail-id-3107264.html" title="碳酸二甲酯廢氣治理"><strong>碳酸二甲酯廢氣治理</strong></a>工藝廢氣達標排放，后續增設一套ＲＴＯ焚燒裝置，經過<a href="/Article-detail-id-2935107.html" title="吸附"><strong>吸附</strong></a>后尾氣濃度比較低，廢氣首先經過阻火器進入進入緩沖罐，然后進入ＲＴＯ預熱段，將廢氣溫度預熱到４００－６００度，此時頂部天然氣噴嘴點火對有機氣體，進行高溫焚燒，溫度達到７００－８００攝氏度，噴嘴降為長明燈狀態，此時有機氣體在高溫狀態瞬間分解氧化，高溫氣體經第二箱體的陶瓷蓄熱體，吸熱后經煙筒高空排放。當第二箱體陶瓷蓄熱體溫度達到預設溫度，底部進氣轉向閥開啟，尾氣從第二箱體進入，經燃燒后從<span style="color:#f33;">一</span>箱體排出。因ＲＴＯ裝置為明火<a href="/Article-detail-id-2950340.html" title="操作"><strong>操作</strong></a>，故進氣管道前段裝有ｖｏｃ濃度檢測儀，當來氣超出預設爆炸極限以下２５％時，旁路風機開啟進行補風，迅速降低來氣濃度，保證<a href="/Article-detail-id-3040794.html" title="焚燒爐"><strong>焚燒爐</strong></a>的<a href="/Article-detail-id-2939716.html" title="安全"><strong>安全</strong></a>性。經冷凝＋ＲＴＯ焚燒工藝，即實現了有機氣體的回收利用，又為ＲＴＯ的運行提供了可靠保證，綜合處理能力達到９８％以上。<a href="/Article-detail-id-3351449.html" title="碳酸二甲酯廢氣"><strong>碳酸二甲酯廢氣</strong></a>治理工藝，該工藝已有成熟運行案例，自投用到現在運行穩定。<img src="http://alipic.files.mozhan.com/ueditor/image/20220406/1649233467113109.jpg" title="1649233467113109.jpg" alt="碳酸二甲酯廢氣治理"/></p> </div> <div class="pager ks-clear"> <span class="iconfont1 iconjiantou newsjiantou-left" style="font-size: 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