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class="Crumb"> <b>您當前的位置：</b><a href="/">首頁</a><em>></em> <a href="/Article-index.html" class="Themefont">下載</a><em>></em><a href="/Articles-72960.html" class="Themefont">解決方案</a> </div> </div>  <div class="row"> <div class="news-nr-box"> <style> body .news-nr-box h1{ font-size:18px; font-family:Airal; text-align:center; line-height:25px; padding: 10px 0; margin:0px; color:#333; } </style> <div class="news1-title"> <h1>碳酸二甲酯和碳酸丙烯酯廢氣治理</h1> <h6> <span>2024-04-16</span> <span>　來自:  淄博清新環?？萍加邢薰? </span> <span style="margin-left:10px;">瀏覽次數:96</span> </h6> </div> <p style="text-indent: 2em; text-align: left;">　碳酸二甲酯生產工藝，國內一般采用環氧丙烷和二氧化碳加催化劑在０．６ｍｐａ，１７０攝氏度下得到粗碳酸丙烯酯，經過負壓精餾提純后得到，精碳酸丙烯酯，此時產生大量<a href="/Article-detail-id-2945299.html" title="廢氣"><strong>廢氣</strong></a>，第二部，碳酸丙烯酯和甲醇在１．０ｍｐａ與甲醇鈉共存，反應生成碳酸二甲酯，碳酸二甲酯和甲醇共沸物，經精餾塔脫出甲醇，回收得到丙二醇，未反應的碳酸丙烯酯和甲醇循環使用，其中在丙二醇減壓精餾過程中產生大量的甲醇廢氣，本工藝系統解決，碳酸丙烯酯生產過程產生的廢氣，及碳酸二甲酯生產過程產生廢氣，最終達標排放。</p><p style="text-indent: 2em; text-align: left;">碳酸二甲酯和碳酸丙烯酯廢氣，甲醇廢氣和碳酸丙烯酯廢氣經絕氧收集，兩條之路分別設有開關閥，可以根據裝置的運行情況，單獨切換，本裝置以<a href="/Article-detail-id-3351449.html" title="碳酸二甲酯廢氣"><strong>碳酸二甲酯廢氣</strong></a>為測算依據，碳酸二甲酯及甲醇廢氣進入<a href="/Article-detail-id-1269834.html" title="冷凝回收裝置"><strong>冷凝回收裝置</strong></a>，采用深度<a href="/Article-detail-id-2942073.html" title="冷凝"><strong>冷凝</strong></a>工藝，根據飽和析出原理，９５％的甲醇可以析出，<a href="/Article-detail-id-1202688.html" title="冷凝回收效率"><strong>冷凝回收效率</strong></a>可以達到９５％以上。經過<a href="/Article-detail-id-1290021.html" title="冷凝回收"><strong>冷凝回收</strong></a>后廢氣進入一套<a href="/Article-detail-id-3398602.html" title="樹脂吸附脫附"><strong>樹脂吸附脫附</strong></a>裝置，經<a href="/Article-detail-id-2776017.html" title="樹脂吸附"><strong>樹脂吸附</strong></a>后氣體排放低于現行排放標準要求。</p><p style="text-indent: 2em; text-align: left;"><a href="/Article-detail-id-3568224.html" title="碳酸二甲酯和碳酸丙烯酯廢氣治理"><strong>碳酸二甲酯和碳酸丙烯酯廢氣治理</strong></a>裝置采用冷凝＋<a href="/Article-detail-id-2935107.html" title="吸附"><strong>吸附</strong></a>的組合工藝。收集的有機混合氣經過收集設施和氣相管路輸送，進入?。郑希谩』厥仗幚硖幚硌b置，ＶＯＣ　回收處理裝置的冷凝單元設置四級<a href="/Article-detail-id-2960639.html" title="冷凝溫度"><strong>冷凝溫度</strong></a>，分別為前置?。保怠?、一級預冷?。场?、二級淺冷－３５℃（雙路，一用一備）、三級冷－７０℃，對尾氣分階段進行降溫處理，使絕大部分?。郑希谩〉玫较嘧円夯?；冷凝余氣進入吸附單元，吸附罐<a href="/Article-detail-id-3580520.html" title="樹脂"><strong>樹脂</strong></a>床攔截冷凝余氣中殘留的碳氫化合物，空氣排放，確保達標。在冷凝單元分段冷凝的配置中，余氣經過冷箱后溫度低至－７０℃，為充分利用這部分冷量，系統設計在<span style="color: rgb(255, 51, 51);">一</span>級前段加裝了汽汽熱交換器的前置換熱器（預冷箱），將后端低溫余氣回傳利用，與進入裝置的高溫氣熱交換，初步降低廢氣溫度，即限度節能降耗。</p><p style="text-indent: 2em; text-align: left;">冷凝過程：</p><p style="text-indent: 2em; text-align: left;">冷凝單元：設置分段冷凝的換熱器，由前置級、第?。薄〖夘A冷級、第?。病〖墱\冷級（雙路，一用一備）和第?。场〖壷欣浼壗M成。前置級將第?。场〖壷欣浼壚淠蟮挠鄽饫淞颗c進入ＶＯＣ　回收處理裝置的常溫<a href="/Article-detail-id-2948720.html" title="油氣"><strong>油氣</strong></a>進行熱量交換，使油氣降低?。怠保啊孀笥?；第?。薄〖夘A冷級，控制尾氣溫度降至?。场孀笥?，使尾氣中絕大部分水蒸汽冷凝液化；第?。病〖墱\冷級，從?。场孀笥医档剑常怠?，使尾氣中部分環氧丙烷組分冷凝液化，該級設置為雙換熱器，一備一用，在因為水汽結霜產生阻力到?。保埃埃埃穑帷∽笥?，進行切換，啟用備用換熱器，同時對停用換熱器進行融霜處理，化霜以后待用；第?。场〖壷欣浼?，從－３５℃降溫至－７０℃，使尾氣中絕大部分?。郑希谩〗M分冷凝液化，效率可達到?。梗担?。本公司冷凝裝置有利于冷凝液化的條件，是設置工況溫度段低于對應組的組分沸點，計算配置的冷負荷能夠滿足冷凝的需要；二是在凝結器結構中，　重組分凝結過程同時的液滴會夾帶輕組分液化，增加冷凝液化效果</p> </div> <div class="pager ks-clear"> <span class="iconfont1 iconjiantou newsjiantou-left" style="font-size: 32px!important;display: none;" ></span> <div class="previous fl"> <span style="padding-top: 5px;">上一條：</span> <a title="碳酸丙烯酯、碳酸二乙酯、碳酸甲乙酯、碳酸二甲酯廢氣治理" class="Themebg Themebghover" href="/Article-detail-id-3563155.html">碳酸丙烯酯、碳酸二乙酯、...</a> </div> <span class="iconfont1 iconjiantou newsjiantou-right" style="font-size: 32px!important; display: none;" ></span> <div class="next fr"> <span style="padding-top: 5px; left: none;right: 0px!important;">下一條：</span> <a title="球形碳質多孔材料球形樹脂炭碳化樹脂吸附脫色高容量吸附劑" class="Themebg Themebghover" 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